Porous NASICON-Type Li3Fe2(PO4)3 Thin Film Deposited by RF Sputtering as Cathode Material for Li-Ion Microbatteries
نویسندگان
چکیده
We report the electrochemical performance of porous NASICON-type Li3Fe2(PO4)3 thin films to be used as a cathode for Li-ion microbatteries. Crystalline porous NASICON-type Li3Fe2(PO4)3 layers were obtained by radio frequency sputtering with an annealing treatment. The thin films were characterized by XRD, SEM, and electrochemical techniques. The chronoamperometry experiments showed that a discharge capacity of 88 mAhg(-1) (23 μAhcm(-2)) is attained for the first cycle at C/10 to reach 65 mAhg(-1) (17 μAhcm(-2)) after 10 cycles with a good stability over 40 cycles.
منابع مشابه
Preparation, characterization and stability of Li-ion conducting Li1.5Al0.5Ge1.5(PO4)3 glass-ceramic with NASICON-type structure
A conducting lithium aluminum germanium phosphate (LAGP) glass-ceramic with a formula of Li1.5Al0.5Ge1.5(PO4)3 was synthesized by melt-quenching method and subsequent crystallization at 850 °C for 8 h. The prepared glass-ceramic was characterized using differential scanning calorimetry (DSC), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and AC impedance techniqu...
متن کاملSelf-standing porous LiMn2O4 nanowall arrays as promising cathodes for advanced 3D microbatteries and flexible lithium-ion batteries
Three-dimensional self-supported cathode nanoarchitectures are the key to develop high-performance thin film lithium-ion microbatteries and flexible lithium-ion batteries. In this work, we have developed a facile “hydrothermal lithiation” strategy to prepare vertically aligned porous LiMn2O4 nanowall arrays, comprising highly crystallized spinel nanoparticles, on various conductive substrates w...
متن کاملHighly Functionalized Lithium-Ion Battery
Future energy demand is an important issue that requires consideration. Lithiumion batteries (LIB) are one of the most popular types of rechargeable battery for portable electronic devices, such as mobile phones, cameras, and laptop computers, and have led to other applications being commercialized. Distributed power generation using renewable energy sources, such as solar photovoltaic (PV), ca...
متن کاملPreparation of Ni current collector and MoS2 cathode in three-dimensional Li ion microbattery based on silicon MCP
Three-dimensional Li ion microbatteries are known for their high surface area which leads to high current and capacity compared to traditional planar batteries. This paper describes economical approaches to prepare half 3D microbatteries based on silicon microchannel plates (MCP). The high aspect ratio silicon MCP is formed by electrochemical etching and a nickel layer is coated onto the silico...
متن کاملA Study of ZnO Buffer Layer Effect on Physical Properties of ITO Thin Films Deposited on Different Substrates
The improvement of the physical properties of Indium Tin Oxide (ITO) layers is quite advantageous in photovoltaic applications. In this study the ITO film is deposited by RF sputtering onto p-type crystalline silicon (c-Si) with (100) orientation, multicrystalline silicon (mc-Si), and glass substrates coated with ZnO and annealed in vacuum furnace at 400°C. Electrical, optical, structural a...
متن کامل